As the subsequent Ngram graph displays, There have been a major increase in frequency of the two "free of" phrases (blue and eco-friendly strains) over the past 100 yrs, Which boost appears to have occur largely for the expenditure of the two "free from" phrases" (crimson and yellow traces):

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people of said city for 6 months next preceding the election, and who shall have paid out their poll tax to reported town chargeable to them for your yr upcoming previous the election at which they assert to vote; also from the free white male inhabitants of Scott county, above the age of twenty one particular yrs, who shall be entrepreneurs of real property lying inside the limitations of mentioned town. ... Accepted March 1, 1854.

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"For free" as a means of claiming "for gratis" is circulating in speech As well as in the popular press for in excess of 50 % a century. I initial took mindful Notice of it in 1970, when Joni Mitchell involved a music titled "For Free" on her album of that calendar year, Ladies in the Canyon

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"Free from," Then again, seems to point much more of an escape in the situation of something which was more externally attached, as in, "Now at last I am free through the bothersome attention of my mother, who would not leave me by itself right until I moved to Ny."

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The letters of an actual term were then utilized to build an acronym. In short, the phrase existed, then the acronym was established in the letters while in the phrase. Backronyms: en.wikipedia.org/wiki/Backronym

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The point that wording "free, white and 21" appears in quotation marks indicates that the writer was invoking free gift card codes generator a formulation that was now (in 1845) a well-recognized phrase—presumably one accustomed to detect the prerequisites for owning arrive of age and entered into the entire legal rights of citizenship in Virginia at that time.